Not if you have a few marbles around. Dump some glass marbles into each sock and tie them with rubber bands, sealing in the marbles. Do laundry as usual and you will find those stained socks aren't stained anymore.
The marbles help clean in a couple of ways. They break the soap bubbles into very small bubbles which increases their cleaning ability. The marbles also help by rubbing the socks from in inside like agitators do. WARNING: Some front load washers may have too much force and smash the marbles.
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